Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028375495> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2028375495 endingPage "59" @default.
- W2028375495 startingPage "47" @default.
- W2028375495 abstract "Reactions between [Pt(C2H4)(PPh3)2] and organotin halides have been investigated. With SnPh2Cl2 the product of insertion into the SnC bond, cis-[PtPh(SnPhCl2)(PPh3)2], was obtained, whereas SnMe2Cl2, SnPhCl3, SnMeCl3 and SnCl4 gave products of insertion into the Sn-Cl bond, viz. cis- and trans-[PtCl((SnClnR3-n)(PPh3)2]. The products were characterised by 31P - {1H} NMR spectroscopy. Compounds of similar stoichiometry [PtR(SnCl3)(PPh3)2] were examined for purposes of comparison and were obtained from SnCl2 and the corresponding chloro complexes. The compounds cis and trans [PtCl(SnCl3) (PPh3)2] were obtained both by the oxidative-addition reaction and the SnCl2 insertion route. A wide variety of similar products were obtained with organotin chlorides and bromides. Competition experiments indicated an order of reactivity in the oxidative addition reaction SnMe4 < SnPh4 < SnMe3Cl < SnPh3Cl, SnMeCl2 < SnPh2Cl2, SnMeCl3 < SnPhCl3 < SnCl4. The presence of radicals in the reaction mixture was not detected by radical transfer or spin-trapping experiments." @default.
- W2028375495 created "2016-06-24" @default.
- W2028375495 creator A5039185826 @default.
- W2028375495 creator A5054040497 @default.
- W2028375495 creator A5074014262 @default.
- W2028375495 date "1979-11-01" @default.
- W2028375495 modified "2023-09-23" @default.
- W2028375495 title "Oxidative addition of tin(IV) compounds to ethylene bis(triphenylphosphine)platinum" @default.
- W2028375495 cites W1131796259 @default.
- W2028375495 cites W1994296858 @default.
- W2028375495 cites W2002168076 @default.
- W2028375495 cites W2078729955 @default.
- W2028375495 cites W2101944485 @default.
- W2028375495 cites W2116634991 @default.
- W2028375495 cites W2149442314 @default.
- W2028375495 cites W2319062674 @default.
- W2028375495 doi "https://doi.org/10.1016/s0022-328x(00)85736-8" @default.
- W2028375495 hasPublicationYear "1979" @default.
- W2028375495 type Work @default.
- W2028375495 sameAs 2028375495 @default.
- W2028375495 citedByCount "50" @default.
- W2028375495 countsByYear W20283754952013 @default.
- W2028375495 countsByYear W20283754952014 @default.
- W2028375495 countsByYear W20283754952017 @default.
- W2028375495 countsByYear W20283754952022 @default.
- W2028375495 crossrefType "journal-article" @default.
- W2028375495 hasAuthorship W2028375495A5039185826 @default.
- W2028375495 hasAuthorship W2028375495A5054040497 @default.
- W2028375495 hasAuthorship W2028375495A5074014262 @default.
- W2028375495 hasConcept C139066938 @default.
- W2028375495 hasConcept C142724271 @default.
- W2028375495 hasConcept C144082473 @default.
- W2028375495 hasConcept C155647269 @default.
- W2028375495 hasConcept C161790260 @default.
- W2028375495 hasConcept C171560689 @default.
- W2028375495 hasConcept C178790620 @default.
- W2028375495 hasConcept C185592680 @default.
- W2028375495 hasConcept C204787440 @default.
- W2028375495 hasConcept C2776910235 @default.
- W2028375495 hasConcept C2777247709 @default.
- W2028375495 hasConcept C2778597550 @default.
- W2028375495 hasConcept C518104683 @default.
- W2028375495 hasConcept C525849907 @default.
- W2028375495 hasConcept C71240020 @default.
- W2028375495 hasConcept C71924100 @default.
- W2028375495 hasConcept C94882840 @default.
- W2028375495 hasConceptScore W2028375495C139066938 @default.
- W2028375495 hasConceptScore W2028375495C142724271 @default.
- W2028375495 hasConceptScore W2028375495C144082473 @default.
- W2028375495 hasConceptScore W2028375495C155647269 @default.
- W2028375495 hasConceptScore W2028375495C161790260 @default.
- W2028375495 hasConceptScore W2028375495C171560689 @default.
- W2028375495 hasConceptScore W2028375495C178790620 @default.
- W2028375495 hasConceptScore W2028375495C185592680 @default.
- W2028375495 hasConceptScore W2028375495C204787440 @default.
- W2028375495 hasConceptScore W2028375495C2776910235 @default.
- W2028375495 hasConceptScore W2028375495C2777247709 @default.
- W2028375495 hasConceptScore W2028375495C2778597550 @default.
- W2028375495 hasConceptScore W2028375495C518104683 @default.
- W2028375495 hasConceptScore W2028375495C525849907 @default.
- W2028375495 hasConceptScore W2028375495C71240020 @default.
- W2028375495 hasConceptScore W2028375495C71924100 @default.
- W2028375495 hasConceptScore W2028375495C94882840 @default.
- W2028375495 hasIssue "1" @default.
- W2028375495 hasLocation W20283754951 @default.
- W2028375495 hasOpenAccess W2028375495 @default.
- W2028375495 hasPrimaryLocation W20283754951 @default.
- W2028375495 hasRelatedWork W1010759469 @default.
- W2028375495 hasRelatedWork W1974589924 @default.
- W2028375495 hasRelatedWork W1987198665 @default.
- W2028375495 hasRelatedWork W2024208184 @default.
- W2028375495 hasRelatedWork W2046070830 @default.
- W2028375495 hasRelatedWork W2056969242 @default.
- W2028375495 hasRelatedWork W2080834094 @default.
- W2028375495 hasRelatedWork W2113440143 @default.
- W2028375495 hasRelatedWork W2952393930 @default.
- W2028375495 hasRelatedWork W2952900404 @default.
- W2028375495 hasVolume "181" @default.
- W2028375495 isParatext "false" @default.
- W2028375495 isRetracted "false" @default.
- W2028375495 magId "2028375495" @default.
- W2028375495 workType "article" @default.