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• W2028387017 startingPage "976" @default.
• W2028387017 abstract "Organic additives influence crystallization processes in a multitude of ways. In biomineralization, e.g. bone or shell, such additives play a crucial role in morphology, and in polymorph and size control. However, the specific interactions between the additives and the growing mineral are in general unknown. Here, a model of bone mineralization, namely the formation of apatite nanocrystals under the influence of poly(acrylic acid), is studied using in situ X-ray diffraction. Since the kinetics of these reactions are very temperature dependent, a new X-ray scattering reaction cell has been developed that allows very high temperature precision, with an r.m.s. variation during operation of ∼0.05 K. The performance of the cell and its use in studying the apatite/poly(acrylic acid) system are discussed. The apatite formation process proceeds via the formation of an amorphous precursor which then crystallizes. It is found that poly(acrylic acid) retards crystallization and reduces the growth rate of the forming crystallites." @default.
• W2028387017 created "2016-06-24" @default.
• W2028387017 creator A5036070589 @default.
• W2028387017 creator A5061212425 @default.
• W2028387017 date "2012-09-13" @default.
• W2028387017 modified "2023-10-16" @default.
• W2028387017 title "Influence of poly(acrylic acid) on apatite formation studied by<i>in situ</i>X-ray diffraction using an X-ray scattering reaction cell with high-precision temperature control" @default.
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• W2028387017 doi "https://doi.org/10.1107/s0021889812036576" @default.
• W2028387017 hasPublicationYear "2012" @default.
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