Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028390821> ?p ?o ?g. }
- W2028390821 endingPage "498" @default.
- W2028390821 startingPage "491" @default.
- W2028390821 abstract "Investigations within the local spin density functional theory (LSDF) of the intermetallic hydride system CeRhSnHx were carried out for discrete model compositions in the range 0.33 ≤xH ≤ 1.33 with the purpose of assessing the change of the cerium valence state in the neighborhood of the experimental hydride composition, CeRhSnH0.8. In agreement with experiment, the analyses of the electronic and magnetic structures and of the chemical bonding properties point to trivalent cerium for 1 ≤xH ≤ 1.33. In contrast, for lower hydrogen amounts the hydride system stays in an intermediate-valent state for cerium, like in CeRhSn. The influence of the insertion of hydrogen is addressed from both the volume expansion and chemical bonding effects. The latter are found to have the main influence on the change of Ce valence character. Spin polarized calculations point to a finite magnetic moment carried by the Ce 4f states; its magnitude increases with xH in the range 1 ≤xH ≤ 1.33." @default.
- W2028390821 created "2016-06-24" @default.
- W2028390821 creator A5011056848 @default.
- W2028390821 creator A5018031437 @default.
- W2028390821 creator A5057320823 @default.
- W2028390821 creator A5068675335 @default.
- W2028390821 date "2008-10-01" @default.
- W2028390821 modified "2023-10-17" @default.
- W2028390821 title "Interplay of negative pressure and hydrogen chemical effects in CeRhSn from first principles" @default.
- W2028390821 cites W1589302465 @default.
- W2028390821 cites W1622398176 @default.
- W2028390821 cites W1966654392 @default.
- W2028390821 cites W1970127494 @default.
- W2028390821 cites W1973022178 @default.
- W2028390821 cites W1979544533 @default.
- W2028390821 cites W1981462343 @default.
- W2028390821 cites W1987543796 @default.
- W2028390821 cites W2001053083 @default.
- W2028390821 cites W2003232804 @default.
- W2028390821 cites W2004140015 @default.
- W2028390821 cites W2007804687 @default.
- W2028390821 cites W2022046858 @default.
- W2028390821 cites W2029667189 @default.
- W2028390821 cites W2030976617 @default.
- W2028390821 cites W2038533471 @default.
- W2028390821 cites W2039197852 @default.
- W2028390821 cites W2052637367 @default.
- W2028390821 cites W2052821860 @default.
- W2028390821 cites W2067318290 @default.
- W2028390821 cites W2068352949 @default.
- W2028390821 cites W2073047123 @default.
- W2028390821 cites W2083222334 @default.
- W2028390821 cites W2088043604 @default.
- W2028390821 cites W2176278854 @default.
- W2028390821 cites W2230728100 @default.
- W2028390821 cites W2949302453 @default.
- W2028390821 cites W2949360018 @default.
- W2028390821 cites W2951295252 @default.
- W2028390821 cites W2952547945 @default.
- W2028390821 doi "https://doi.org/10.1140/epjb/e2008-00369-4" @default.
- W2028390821 hasPublicationYear "2008" @default.
- W2028390821 type Work @default.
- W2028390821 sameAs 2028390821 @default.
- W2028390821 citedByCount "5" @default.
- W2028390821 countsByYear W20283908212013 @default.
- W2028390821 countsByYear W20283908212015 @default.
- W2028390821 crossrefType "journal-article" @default.
- W2028390821 hasAuthorship W2028390821A5011056848 @default.
- W2028390821 hasAuthorship W2028390821A5018031437 @default.
- W2028390821 hasAuthorship W2028390821A5057320823 @default.
- W2028390821 hasAuthorship W2028390821A5068675335 @default.
- W2028390821 hasBestOaLocation W20283908214 @default.
- W2028390821 hasConcept C121332964 @default.
- W2028390821 hasConcept C147597530 @default.
- W2028390821 hasConcept C147789679 @default.
- W2028390821 hasConcept C152365726 @default.
- W2028390821 hasConcept C159467904 @default.
- W2028390821 hasConcept C168900304 @default.
- W2028390821 hasConcept C178213299 @default.
- W2028390821 hasConcept C178790620 @default.
- W2028390821 hasConcept C185592680 @default.
- W2028390821 hasConcept C191897082 @default.
- W2028390821 hasConcept C192562407 @default.
- W2028390821 hasConcept C27501479 @default.
- W2028390821 hasConcept C2777961443 @default.
- W2028390821 hasConcept C2780026712 @default.
- W2028390821 hasConcept C512968161 @default.
- W2028390821 hasConcept C523597863 @default.
- W2028390821 hasConcept C86025842 @default.
- W2028390821 hasConcept C97355855 @default.
- W2028390821 hasConceptScore W2028390821C121332964 @default.
- W2028390821 hasConceptScore W2028390821C147597530 @default.
- W2028390821 hasConceptScore W2028390821C147789679 @default.
- W2028390821 hasConceptScore W2028390821C152365726 @default.
- W2028390821 hasConceptScore W2028390821C159467904 @default.
- W2028390821 hasConceptScore W2028390821C168900304 @default.
- W2028390821 hasConceptScore W2028390821C178213299 @default.
- W2028390821 hasConceptScore W2028390821C178790620 @default.
- W2028390821 hasConceptScore W2028390821C185592680 @default.
- W2028390821 hasConceptScore W2028390821C191897082 @default.
- W2028390821 hasConceptScore W2028390821C192562407 @default.
- W2028390821 hasConceptScore W2028390821C27501479 @default.
- W2028390821 hasConceptScore W2028390821C2777961443 @default.
- W2028390821 hasConceptScore W2028390821C2780026712 @default.
- W2028390821 hasConceptScore W2028390821C512968161 @default.
- W2028390821 hasConceptScore W2028390821C523597863 @default.
- W2028390821 hasConceptScore W2028390821C86025842 @default.
- W2028390821 hasConceptScore W2028390821C97355855 @default.
- W2028390821 hasIssue "4" @default.
- W2028390821 hasLocation W20283908211 @default.
- W2028390821 hasLocation W20283908212 @default.
- W2028390821 hasLocation W20283908213 @default.
- W2028390821 hasLocation W20283908214 @default.
- W2028390821 hasOpenAccess W2028390821 @default.
- W2028390821 hasPrimaryLocation W20283908211 @default.
- W2028390821 hasRelatedWork W2005864854 @default.
- W2028390821 hasRelatedWork W2009094181 @default.
- W2028390821 hasRelatedWork W2015556608 @default.