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- W2028394887 abstract "Raman spectroscopic investigations of deuterated γ-glycine, carried out up to 21 GPa, indicate emergence of a new phase, which is similar to the δ-phase, reported to be formed from the undeuterated γ-glycine at 3 GPa and the transformation to this phase is complete by 6 GPa. Observed pressure -induced variations in CD2 and N−D stretching modes indicate significant changes in the hydrogen-bonding interactions. Around ∼15 GPa, splitting of CD2 and C−C stretching modes and discontinuous changes in the slope of CO2 and N−D stretching modes indicate another structural rearrangement across this pressure. The Raman spectra of retrieved phase at ambient conditions suggest that it may be a layered structure similar to the ζ-phase reported to be formed on decompression of the nondeuterated δ-glycine." @default.
- W2028394887 created "2016-06-24" @default.
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- W2028394887 date "2008-11-17" @default.
- W2028394887 modified "2023-09-26" @default.
- W2028394887 title "High Pressure Raman Spectroscopic Study of Deuterated γ-Glycine" @default.
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- W2028394887 doi "https://doi.org/10.1021/jp806381e" @default.
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