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• W2028408068 abstract "Under high-pressure high-temperature conditions, the title compounds with 4, 5, 6, or 8 SiSi contacts are formed. The interatomic distances can be scaled to the number of homonuclear neighbors in the silicide framework. Analysis of the chemical bonding reveals multicenter bonds between metal and Si atoms (see figure for CeSi5: Si blue and green, Ce red) and a contribution of semi-core states (the penultimate shell) of Ce to the chemical bonding." @default.
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• W2028408068 date "2010-10-15" @default.
• W2028408068 modified "2023-09-25" @default.
• W2028408068 title "Unusual Silicon Connectivities in the Binary Compounds GdSi5, CeSi5, and Ce2Si7" @default.
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• W2028408068 doi "https://doi.org/10.1002/anie.201003490" @default.
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