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- W2028430384 abstract "Measurements of steady state current voltage curves and transient resistance were carried out with Pt or Au point electrodes on CuInS2 and CuInSe2 (polycrystalline and single crystal samples) in the temperature range 25–150°C. The results show that changes in non-stoichiometry of CuInS2 and CuInSe2 due to mobility of copper ions occur at these temperatures if electrical potential differences are applied. From the form of the steady state current voltage relation it was concluded that increasing copper concentration leads to a change from p- to n-type conduction in originally p-type samples of CuInS2 and CuInSe2 at the contact with the point electrode. Both compounds (except single crystals of CuInS2) showed copper deposits at cathodically polarized point electrodes for voltages above 500 mV. This is a good indication for ionic conductivity of copper at ambient temperature. Samples with small values of the electrical conductivity yielded the highest values for the chemical diffusion coefficients. At 25°C, typical values for CuInS2 range between D̃ = 2.3 × 10−9 and 3.2 × 10−6 cm2/s and for CuInSe2 between D̃ = 4.0 × 10−9 and 2.7 × 10−5 cm2/s." @default.
- W2028430384 created "2016-06-24" @default.
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- W2028430384 date "1988-09-01" @default.
- W2028430384 modified "2023-10-03" @default.
- W2028430384 title "Chemical diffusion coefficients and stability of CuInS2 and CuInSe2 from polarization measurements with point electrodes" @default.
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- W2028430384 doi "https://doi.org/10.1016/0167-2738(88)90340-2" @default.
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