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- W2028451621 abstract "Au@Ag core–shell nanorods with tunable end facets are obtained by coating Au bipyramids (BPs) with Ag. The resultant nanorods exhibit a pentatwinned crystal structure with tips terminated with either {110} or {111} facets. The control over the end facets is achieved by varying the capping agents and tuning the reduction rate of Ag. Specifically, when Ag is reduced slowly, Au@Ag nanorods with flat {110} end facets are formed with cetyltrimethylammonium bromide (CTAB) as the capping agent. If CTAB is replaced with cetyltrimethylammonium chloride (CTAC), Au@Ag nanorods with tips terminated with {111} facets are obtained. However, at a high Ag reduction rate, dumbbell-shaped Au@Ag nanorods are formed, with either CTAB or CTAC as the capping agent. The morphological evolution of the nanorods in each case is closely followed and a growth mechanism is proposed." @default.
- W2028451621 created "2016-06-24" @default.
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- W2028451621 date "2013-08-09" @default.
- W2028451621 modified "2023-09-26" @default.
- W2028451621 title "Growth of Au@Ag Core-Shell Pentatwinned Nanorods: Tuning the End Facets" @default.
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- W2028451621 doi "https://doi.org/10.1002/chem.201301753" @default.
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