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- W2028456273 abstract "The participation of silicon d orbitals in the bonding of cyclopropylsilane and vinyl-silane has been investigated by ab initio determination of the geometric and electronic structures of these molecules. (pd) π-bonding in the CSi bonds was found to be negligible. In cyclopropylsilane, both the large ring deformations induced by interaction with the ring and other structural features can be explained on the basis of silicon acting, not as an electron acceptor, but as an electron donor to both the σ- and the π-systems of the ring. A new silicon basis set is developed and tested on the title compounds and methylsilane." @default.
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- W2028456273 date "1979-01-01" @default.
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- W2028456273 title "Participation of silicon d orbitals in bonding as determined from the geometric and electronic structures of cyclopropylsilane and vinylsilane" @default.
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- W2028456273 doi "https://doi.org/10.1016/0022-2860(79)80243-4" @default.
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