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• W2028476020 endingPage "378" @default.
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• W2028476020 abstract "Using grazing incidence surface X-ray diffraction, we have investigated the superstructure of TiO2(100)-(1 × 3) (rutile). The analysis of both fractional order superlattice rods and integer order crystal truncation rods (229 independent reflections in total), leads to a structure model which can basically be described as the formation of {110} micro-facets on the surface. In addition, strong lateral and vertical relaxations of the titanium and oxygen atoms exist down to about 9 Å below the surface. The surface titanium atoms are found to reside in different environments, namely in three-, five- and six-fold oxygen coordination and in a bridge site. Furthermore, we determined a 40% occupancy of an interstitial site occupied by one titanium atom per (1 × 3) unit cell. The surface stoichiometry is given by the formula TiO1.68. Our structure model is significantly different from previous X-ray data [P. Zschack et al., Surf. Sci. 262 (1992) 395], but is in good agreement with spectroscopic experiments and scanning tunneling microscopy investigations." @default.
• W2028476020 created "2016-06-24" @default.
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• W2028476020 date "1998-02-01" @default.
• W2028476020 modified "2023-10-18" @default.
• W2028476020 title "Surface X-ray structure analysis of the TiO2(100)-(1 × 3) reconstruction" @default.
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• W2028476020 doi "https://doi.org/10.1016/s0039-6028(98)80042-3" @default.
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