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- W2028482841 abstract "The E(0+) → B(0+) emission spectrum of 81Br37Cl in the presence of Ar occurs near 3270 Å and is dominated by emission from v′ = 0 and 1. A rotational analysis of four v′-v″ bands reveals anomalous behavior in the rotational and centrifugal distortion constants for the E state. This behavior is attributed to electronic-coriolis interaction with the unseen β(1) state—a member, with E, of the lowest group of three ion-pair states. A deperturbation analysis locates the E state at Re = 3.042(2) Å, with T0 = 48 854.29(5) cm−1. The β state is predicted to lie 24(3) cm−1 below E, with Re = 3.082(3) Å. The B state is known from earlier work to display a barrier as a consequence of a strongly avoided intersection with another 0+ state. The highest v″ level observed in the E → B system is v″ = 9, but the strong 1–9 band shows no discernible fine structure, an effect we attribute to the broadness of the barrier-bound resonances in this level. Similar effects are responsible for the breaking off of the rotational lines in the 0–8 band around J = 70. Computational simulation of these resonances indicates that the barrier is located near 3.4 Å and 18 550(20) cm−1 above the minimum of the ground state. A reassessment of existing predissociation data for the B state leads to a revised estimate of 18 245(15) cm−1 for the ground state dissociation energy." @default.
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- W2028482841 date "1988-11-01" @default.
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- W2028482841 title "The E → B transition in 81Br37Cl" @default.
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- W2028482841 doi "https://doi.org/10.1016/0022-2852(88)90067-7" @default.
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