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- W2028486294 abstract "The bielectrode technique has been used to measure directly hydrogen solubility isotherms of the PdH and PdAgH systems. By applying small constant current densities, thin palladium or PdAg foils can be loaded continuously and homogeneously with hydrogen from one side in the electrochemical double cell, while at the other side the open-circuit potential is followed as a measure for the logarithm of pressure. For PdAg alloys the p−c isotherms obtained electrochemically agree well with those obtained from gas volumetric measurements. For the PdH system, however, anomalies occur when current densities greater than 1 mA are applied. The β phase boundary seems to be shifted to smaller concentration values, where coexistence of the two phases (α and β) is expected. This shift, which depends on the sample preparation conditions and the current densities applied in the experiment, is obviously due to a favoured growth of β phase crystallites in the diffusion direction." @default.
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- W2028486294 date "1991-08-01" @default.
- W2028486294 modified "2023-09-27" @default.
- W2028486294 title "Electrochemical isotherm measurements on the PdH and PdAgH systems" @default.
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- W2028486294 doi "https://doi.org/10.1016/0022-5088(91)90208-l" @default.
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