FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028494431> ?p ?o ?g. }

• W2028494431 endingPage "4881" @default.
• W2028494431 startingPage "4873" @default.
• W2028494431 abstract "Reactions between the potentially pentadentate (N(2)O(3)), trianionic double Schiff-base ligand 2,6-bis[[(2-hydroxyethyl)imino]methyl]-4-methylphenol (H(3)L) and Cu(CH(3)CO(2))(2) or Cu(ClO(4))(2), in the presence of NaN(3), give novel coordination polymers with chain {[Cu(2)(H(2)L)(N(3))(3)](2).H(2)O}(n) (1) or sheet [Cu(2)(H(2)L)(N(3))(3)](n) (2) and [Cu(2)(HL)(N(3))](n)[ClO(4)](n) (3) structures, respectively. These clusters are comprised of repeating dinuclear units (1) or their dimers (2 and 3). In these compounds, H(3)L acts as a tridentate (N(2)O) monoanionic (1), tetradentate (ON(2)O) monoanionic (2), or pentadentate (O(3)N(2)) dianionic (3) ligand. Compound [Cu(2)(HL)(N(3))(2)(H(2)O)].0.5CH(3)OH (4) formed from the reaction of Cu(CH(3)CO(2))(2) with H(3)L under reflux, which did not afford crystals suitable for X-ray studies. X-ray structure determinations have revealed that the basic building block in 1-3 comprises two copper centers bridged through one mu-phenolate O atom from H(2)L(-) or HL(2-) and one mu-azido(N1,N1) ion. Compounds 1-3 unveil three different ways in which this Cu(2) basic unit may be organized in the crystalline phase at the supramolecular level through a variety of bridging interactions involving additional azide ligands or alkoxide groups from the side arms of the ligand H(3)L. Bulk magnetization measurements have served to demonstrate that the magnetic interactions are completely dominated by the strong antiferromagnetic coupling occurring within the Cu(2) building block, with coupling constants ranging from 330 to 560 cm(-1) (in the H = -JS(1)S(2) convention). These results together have been incorporated with data from the few related copper dimers reported exhibiting the same bridging pattern into a study aimed at extracting possible magnetostructural correlations within this Cu(2) unit. An earlier predicted correlation between J and the angle formed by the phenoxide bridge and the Cu(2) core has been identified for the first time." @default.
• W2028494431 created "2016-06-24" @default.
• W2028494431 creator A5007192619 @default.
• W2028494431 creator A5012555611 @default.
• W2028494431 creator A5054787606 @default.
• W2028494431 creator A5054944130 @default.
• W2028494431 creator A5069726174 @default.
• W2028494431 creator A5069994955 @default.
• W2028494431 creator A5071006730 @default.
• W2028494431 date "2009-04-20" @default.
• W2028494431 modified "2023-10-08" @default.
• W2028494431 title "Copper Coordination Polymers Based on Single-Chain or Sheet Structures Involving Dinuclear and Tetranuclear Copper(II) Units: Synthesis, Structures, and Magnetostructural Correlations" @default.
• W2028494431 cites W1850857830 @default.
• W2028494431 cites W1966417790 @default.
• W2028494431 cites W1967800614 @default.
• W2028494431 cites W1967857939 @default.
• W2028494431 cites W1972335601 @default.
• W2028494431 cites W1975360649 @default.
• W2028494431 cites W1975646186 @default.
• W2028494431 cites W1977441978 @default.
• W2028494431 cites W1983536121 @default.
• W2028494431 cites W1986031004 @default.
• W2028494431 cites W1986757683 @default.
• W2028494431 cites W1987946870 @default.
• W2028494431 cites W1988795295 @default.
• W2028494431 cites W1990654323 @default.
• W2028494431 cites W1997557995 @default.
• W2028494431 cites W2003514580 @default.
• W2028494431 cites W2003612736 @default.
• W2028494431 cites W2005367838 @default.
• W2028494431 cites W2006038032 @default.
• W2028494431 cites W2007512432 @default.
• W2028494431 cites W2008141942 @default.
• W2028494431 cites W2008520425 @default.
• W2028494431 cites W2011460678 @default.
• W2028494431 cites W2025091598 @default.
• W2028494431 cites W2028984595 @default.
• W2028494431 cites W2036115336 @default.
• W2028494431 cites W2038409508 @default.
• W2028494431 cites W2042404011 @default.
• W2028494431 cites W2044979436 @default.
• W2028494431 cites W2050707336 @default.
• W2028494431 cites W2058528394 @default.
• W2028494431 cites W2062792508 @default.
• W2028494431 cites W2066223077 @default.
• W2028494431 cites W2071202770 @default.
• W2028494431 cites W2071236931 @default.
• W2028494431 cites W2071678366 @default.
• W2028494431 cites W2079207256 @default.
• W2028494431 cites W2080665513 @default.
• W2028494431 cites W2083046671 @default.
• W2028494431 cites W2084975102 @default.
• W2028494431 cites W2089740902 @default.
• W2028494431 cites W2090155847 @default.
• W2028494431 cites W2091385430 @default.
• W2028494431 cites W2092308338 @default.
• W2028494431 cites W2092596900 @default.
• W2028494431 cites W2095652648 @default.
• W2028494431 cites W2105249240 @default.
• W2028494431 cites W2110241495 @default.
• W2028494431 cites W2134175666 @default.
• W2028494431 cites W2135374860 @default.
• W2028494431 cites W2142199780 @default.
• W2028494431 cites W2145657324 @default.
• W2028494431 cites W2146099614 @default.
• W2028494431 cites W2151675857 @default.
• W2028494431 cites W2153267063 @default.
• W2028494431 cites W2157986221 @default.
• W2028494431 cites W2164043498 @default.
• W2028494431 cites W2499813924 @default.
• W2028494431 cites W2951702750 @default.
• W2028494431 cites W633950491 @default.
• W2028494431 doi "https://doi.org/10.1021/ic900240y" @default.
• W2028494431 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19378941" @default.
• W2028494431 hasPublicationYear "2009" @default.
• W2028494431 type Work @default.
• W2028494431 sameAs 2028494431 @default.
• W2028494431 citedByCount "29" @default.
• W2028494431 countsByYear W20284944312012 @default.
• W2028494431 countsByYear W20284944312013 @default.
• W2028494431 countsByYear W20284944312014 @default.
• W2028494431 countsByYear W20284944312015 @default.
• W2028494431 countsByYear W20284944312017 @default.
• W2028494431 countsByYear W20284944312018 @default.
• W2028494431 countsByYear W20284944312019 @default.
• W2028494431 countsByYear W20284944312020 @default.
• W2028494431 countsByYear W20284944312022 @default.
• W2028494431 crossrefType "journal-article" @default.
• W2028494431 hasAuthorship W2028494431A5007192619 @default.
• W2028494431 hasAuthorship W2028494431A5012555611 @default.
• W2028494431 hasAuthorship W2028494431A5054787606 @default.
• W2028494431 hasAuthorship W2028494431A5054944130 @default.
• W2028494431 hasAuthorship W2028494431A5069726174 @default.
• W2028494431 hasAuthorship W2028494431A5069994955 @default.
• W2028494431 hasAuthorship W2028494431A5071006730 @default.
• W2028494431 hasConcept C11111787 @default.
• W2028494431 hasConcept C115624301 @default.
• W2028494431 hasConcept C116569031 @default.

• next