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- W2028499897 abstract "The influence of oppositely charged polyelectrolytes and copolymers of different charge density and polyanion-polycation mixtures on the preordered lamellar liquid crystalline system sodium dodecylsulfatedecanolwater due to Coulombic interactions with special accentuation of aggregation and adsorption phenomena was examined. Small-angle X-ray results and rheological investigations are discussed with regard to changes in the interlayer spacing after introducing the polymers at various concentrations. The liquid crystalline phase was maintained, but the preformed lamellar structure was modified via penetration of the macromolecules between the hydrocarbon chains of the surfactant molecules. In the case of the polycation, strong Coulombic interactions cause a so-called “frozen” structure, whereas for the copolymers with decreasing charge density a “loop” conformation becomes possible, resulting in significantly increased interlayer spacings. Polyanions and polyanion-polycation mixtures showed phenomena of phase separation." @default.
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- W2028499897 date "1997-05-01" @default.
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- W2028499897 title "Polymers in lyotropic liquid crystalline systems" @default.
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- W2028499897 doi "https://doi.org/10.1016/s0927-7757(96)03797-1" @default.
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