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- W2028528054 abstract "The laser-induced fluorescence spectrum of palladium monoboride (PdB) in the visible region between 465 and 520 nm has been observed and analyzed. Gas-phase PdB molecules were produced by the reaction of diborane (B2H6) seeded in argon with laser ablated palladium atoms. Thirteen vibrational bands have been recorded, which included transitions of both Pd10B and Pd11B isotopic species. These bands belong to the [19.7]2Σ+–X2Σ+ system, with ground X2Σ+ state bond length, ro, determined to be 1.7278 Å. A molecular orbital energy level diagram was used to understand the observed ground and excited electronic states. This work represents the first experimental investigation of the electronic spectroscopy of the PdB molecule." @default.
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- W2028528054 date "2012-11-08" @default.
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- W2028528054 title "Electronic Transition of Palladium Monoboride" @default.
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- W2028528054 doi "https://doi.org/10.1021/jp309093f" @default.
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