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• W2028534836 abstract "Guided ion beam mass spectrometry is used to investigate the kinetic energy dependence of the bimolecular reactions of CO2 and CO with Mo+, MoO+, and MoO2+. To obtain a more complete understanding of these systems, we probe MoO2+ and the intermediates, Mo(CO2)+, OMo(CO)+, OMo(CO2)+, and O2Mo(CO)+, by collisional activation experiments with Xe. Thermochemical analyses of the reaction cross sections obtained in this study yield (in eV) D0(Mo+−CO2) = 0.51 ± 0.07, D0(OMo+−CO2) = 0.77 ± 0.03, D0(OMo+−CO) = 0.80 ± 0.08, D0(O2Mo+−CO) = 0.92 ± 0.17, and D0(OMo+−O) = 5.57 ± 0.14 eV. Additional features in some reaction cross sections are assigned to the formation of excited electronic states of the products, thereby allowing a speculative measurement of excitation energies for states of MoO+ and MoO2+." @default.
• W2028534836 created "2016-06-24" @default.
• W2028534836 creator A5012564920 @default.
• W2028534836 creator A5023872786 @default.
• W2028534836 date "1998-12-01" @default.
• W2028534836 modified "2023-09-25" @default.
• W2028534836 title "Reactions of CO and CO₂ with Gas-Phase Mo⁺, MoO⁺, and MoO₂⁺" @default.
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• W2028534836 doi "https://doi.org/10.1021/jp983694v" @default.
• W2028534836 hasPublicationYear "1998" @default.
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