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- W2028547533 abstract "Members of a new family of lanthanide complexes of the cone-shaped podand 1 and the barrel-shaped cryptand 2, based on calix[4]arenes incorporating bipyridine N,N′-dioxide chromophores, have been synthesized and characterized. The complexes were found to be stable in water and coordinating solvents. High molar absorption coefficients {ϵ = 28000 and 36000 M−1cm−1 for [Eu(1)]3+ and [Eu(2)]3+, respectively} and high metal luminescence quantum yields {Φ = 0.19 and 0.11 for [Eu(1)]3+ and [Eu(2)]3+, respectively} were obtained. The effect of OH oscillators, attached at the lower rim of the calixarenes, on the non-radiative deactivation to the ground state has been demonstrated." @default.
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- W2028547533 date "1998-12-01" @default.
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- W2028547533 title "Synthesis of Functionalized Calix[4]arene Ligands Incorporating BipyridineN,N′-Dioxide Chromophores and Luminescence of Their Lanthanide Complexes" @default.
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- W2028547533 doi "https://doi.org/10.1002/(sici)1099-0682(199812)1998:12<1959::aid-ejic1959>3.0.co;2-0" @default.
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