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- W2028554132 abstract ": The synthesis of a novel mono-squaramide-functionalised pillar[5]arene 1a is reported, by which n-hexylphosphonic acid (HPA) or n-heptanoic acid (HA) could be recognised. The results of 1H NMR titration, Job Plot, ESI-MS and 2D NMR experiments reveal that 1a forms a 1:1 stoichiometric complex with HPA and HA, respectively, and its association constants (log K/M− 1) with HPA and HA are determined to be 3.83 ± 0.05 and 1.98 ± 0.04, respectively, suggesting much stronger binding ability of 1a with HPA over HA. To compare with 1a, 1b with the electron-withdrawing group (CF3) on the phenyl ring of squaramide moiety is synthesised as well, which shows the similar selective binding ability for HPA and HA but with a little stronger binding ability than 1a." @default.
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- W2028554132 date "2015-01-23" @default.
- W2028554132 modified "2023-10-17" @default.
- W2028554132 title "The recognition of n-alkyl phosphonic or carboxylic acid by mono-squaramide-functionalised pillar[5]arenes" @default.
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- W2028554132 doi "https://doi.org/10.1080/10610278.2014.999769" @default.
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