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• W2028559042 abstract "Abstract Two complexes formulated as {[Cd(btec)0.5(tmb)H2O]·4H2O}n (1) and {[Cd(H2btec)(tmb)(H2O)]·2H2O}n (2) (H4btec = 1,2,4,5-benzenetetracarboxylic acid, tmb = 2-((1H-1,2,4-triazol-1-yl)methyl)-1H-benzimidazole) have been synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. Single crystal X-ray diffraction shows that 1 has a 2-D layer structure in which tmb bridges and all of the carboxylates from 1,2,4,5-benzenetetracarboxylate chelate. In 2 Cd(II) ions are bridged by monodentate carboxylates leading to a 2-D layer structure with all tmb ligands coordinated monodentate to Cd(II), hanging at two sides of the layers. Complexes 1 and 2 are further extended to 3-D supramolecular structures by hydrogen bonding interactions. Luminescent properties have been investigated in the solid state at room temperature. Keywords: 2-((1H-1,2,4-Triazol-1-yl)methyl)-1H-benzimidazoleCadmium complexCrystal structure Acknowledgment We gratefully acknowledge the financial support by the National Natural Science Foundation of China (No. J0830412)." @default.
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• W2028559042 date "2013-03-01" @default.
• W2028559042 modified "2023-10-18" @default.
• W2028559042 title "Syntheses, crystal structures, and fluorescent properties of two 2-D Cd(II) complexes based on 2-((1<i>H</i>-1,2,4-triazol-1-yl)methyl)-1<i>H</i>-benzimidazole and 1,2,4,5-benzenetetracarboxylate" @default.
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• W2028559042 doi "https://doi.org/10.1080/00958972.2013.769210" @default.
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