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- W2028596233 abstract "Zum ersten Mal liegen die Formalpotentiale einer Serie von festen Metallhexacyanometallaten (M + ) n M′[M″(CN) 6 ] vor (M + Li + , K + , Na + , Rb + , Cs + ; M′ Ag, Al, Cd, Co, Cr, Cu, Fe, Ga, In, Mn, Ni, Pb; M″ Cr, Fe, Mn). Es existiert eine lineare Korrelation zwischen dem Ionenpotential ϕ z/r eff der stickstoffgebundenen Ionen M′ und den Formalpotentialen der Hexacyanometallat‐Ionen. Diese ist eine Folge der sich mit zunehmender Säure‐Base‐Wechselwirkung verstärkenden π‐Rückbindung zwischen dem Stickstoffatom der Cyanidionen und den Metallionen M′." @default.
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- W2028596233 date "1995-12-15" @default.
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- W2028596233 title "Die Formalpotentiale fester Metallhexacyanometallate" @default.
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