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• W2028609152 abstract "NMR study has shown that DNA oligonucleotide d(G(3)T(4)G(4)) adopts an asymmetric bimolecular G-quadruplex structure in solution. The structure of d(G(3)T(4)G(4))(2) is composed of three G-quartets, overhanging G11 residue and G3, which is part of the loop. Unique structural feature of d(G(3)T(4)G(4))(2) fold is the orientation of the two loops. Thymidine residues T4-T7 form a diagonal loop, whereas T15-T18 form an edge type loop. The G-quadruplex core of d(G(3)T(4)G(4))(2) consists of two stacked G-quartets with syn-anti-anti-anti alternation of dG residues and one G-quartet with syn-syn-anti-anti alternation. Another unusual structural feature of d(G(3)T(4)G(4))(2) is a leap between G19 and G20 over the middle G-quartet and chain reversal between G19 and G20 residues. The presence of one antiparallel and three parallel strands reveals the hitherto unknown G-quadruplex folding motif consisting of antiparallel/parallel strands and diagonal as well as edge type loops. Further examination of the influence of different monovalent cations on the folding of d(G(3)T(4)G(4)) showed that it forms a bimolecular G-quadruplex in the presence of K+, Na+, and NH4+ ions with the same general fold." @default.
• W2028609152 created "2016-06-24" @default.
• W2028609152 creator A5027486871 @default.
• W2028609152 creator A5059664157 @default.
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• W2028609152 date "2003-06-07" @default.
• W2028609152 modified "2023-09-25" @default.
• W2028609152 title "Small Change in a G-Rich Sequence, a Dramatic Change in Topology: New Dimeric G-Quadruplex Folding Motif with Unique Loop Orientations" @default.
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• W2028609152 doi "https://doi.org/10.1021/ja0348694" @default.
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