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- W2028627056 abstract "The series of α,ω-dibromopermethylpolysilanes, Br(SiMe2)nBr, (n = 2−6) has been prepared by the action of bromine on dodecamethylcyclohexasilane. The mass spectra of these compounds, of the corresponding chlorine compounds Cl(SiMe2)nCl (n = 2−6), and of the 1-chloropermethylpolysilanes Cl(SiMe2)Me (n = 2, 3, 4, 6) have been recorded at 14 and 70 eV. For compounds with n > 3, the formation of the ions Si3Me6X+ and Si4Me8X+ (X = Cl, Br) is strongly favored, with these ions being major or base peaks in the spectra. It is proposed that the stability of these ions is due to cyclization and bridging:" @default.
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- W2028627056 date "1977-11-01" @default.
- W2028627056 modified "2023-09-23" @default.
- W2028627056 title "The preparation of α,ω-dibromopermethylpolysilanes and characterization of these and related chloropermethylpolysilanes by mass spectrometry" @default.
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- W2028627056 doi "https://doi.org/10.1016/s0022-328x(00)93188-7" @default.
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