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- W2028629258 abstract "The rate at which CO replaces O2 from combination with O2Hb in cells and solution has been measured for different species. Red cells studied were those of the human adult and newborn rabbit, dog, cat, horse, goat and toad. At 37 °C the cell reaction rate was more affected by the rate in solution than by the size of the cells. At lower temperatures the cell and solution rates were closer together and at 25 °C the replacement reaction was as fast in the large cells of the toad as in some mammalian cells. The energy of activation (E) of the replacement reaction in solution was approximately 20 kcal. Mole-1 for the three hemoglobins in which it was measured. For the reaction in red cells, E was in the range predicted from E in solution. The rates of the replacement reaction were applied to measurements of Dm and Vc by the method of Roughton and Forster. It was found that Vc can be measured without knowledge of the cell reaction rate provided that the solution rate at low CO tensions is known. Some workers have used the rate of the replacement reaction in man at 37 °C when making measurements on other species or at other temperatures. It has been shown that this can lead to errors in Dm and Vc." @default.
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- W2028629258 title "Rate at which CO replaces O2 from O2Hb in red cells of different species" @default.
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- W2028629258 doi "https://doi.org/10.1016/0034-5687(69)90068-1" @default.
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