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• W2028632171 abstract "Durch Reaktion von Cp2TiCl2 bzw. Cp2M (M  V, Cr, Mn; Cp  C5H5) mit Me3Si-N  N-SiMe3 bilden sich folgende Komplexe: Cp2TiNN(SiMe3)2 (2), Cp2VNN(SiMe3)2 (1), [CpCrNN(SiMe3)2]2 (3), [CpMnNN(SiMe3)2]2 (4). Während der Bis(trimethylsilyl)isodiazen-Ligand im Falle von 2 (und wahrscheinlich 1) terminal an das Metall gebunden ist, verbrückt NN(SiMe3)2 laut Röntgenstrukturanalyse im Falle von 4 (und wahrscheinlich 3) zwei Metallatome. [Bis(trimethylsilyl)isodiazene](cyclopentadienyl)metal Complexes: Synthesis and Structure1) The following complexes are formed by the reaction of Cp2TiCl2 or Cp2M (M  V, Cr, Mn; Cp  C5H5) with Me3Si-N  N-SiMe3: Cp2TiNN(SiMe3)2 (2), Cp2VNN(SiMe3)2 (1), [CpCrNN(SiMe3)2]2 (3), [CpMnNN(SiMe3)2]2 (4). While in the case of 2 (and possibly 1) the bis(trimethylsilyl)isodiazene ligand is terminally bound to the metal, according to X-ray analysis in the case of 4 (and possibly 3) NN(SiMe3)2 combines two metal atoms." @default.
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• W2028632171 date "1978-07-01" @default.
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• W2028632171 title "[Bis(trimethylsilyl)isodiazen](cyclopentadienyl)metall‐Komplexe: Synthese und Struktur" @default.
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• W2028632171 doi "https://doi.org/10.1002/cber.19781110726" @default.
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