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- W2028644929 abstract "The formation of C-Li-O-S-C five-membered rings is the most important characteristic in the double lithiation of bis(trimethylsilyl)methyl phenyl sulfone 1 (R R′ H), in which 2 is formed. 2 is present as dimer in the crystal; the two monomers are coupled via Li2O2 four-membered rings. The structure in the crystal is stabilized by four ether ligands per dimer. There are no interactions between Li⊕ and the “carbanionic” C(SiMe3)2 groups. The sp2 orbital of the orthoC-atom of 2 points to the midpoint between the two Li⊕ ions." @default.
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- W2028644929 date "1987-12-01" @default.
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- W2028644929 title "X‐Ray Structure Analysis of the Li<sub>2</sub>‐Compound of Bis(trimethylsilyl)metnyl Phenyl Sulfone; Structural Units of an α‐Sulfonyl‐ and a Complex‐Stabilized <i>ortho</i>‐Sulfonyl‐“Carbanion”" @default.
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- W2028644929 doi "https://doi.org/10.1002/anie.198712871" @default.
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