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- W2028651663 endingPage "341" @default.
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- W2028651663 abstract "Liquid structures of 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide [BMI+][TFSA−] and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)amide [BDMI+][TFSA−] were studied by large-angle X-ray scattering (LAXS) experiments to elucidate methyl substitution effect at the C2 position of imidazolium cation on the long-range ordering of the ionic liquids. Radial distribution functions for both ionic liquids showed that the intermolecular correlations of ca. 5.5 and 10 Å are significantly different from each other, unlike that of ca. 15 Å. MD simulations were also performed. It turns out that the methyl substitution at the C2 position of imidazolium causes variation of the orientation of the nearest neighboring ion–ion interactions without significant changes in the long-range ordering, probably longer than 15 Å, of the ionic liquids." @default.
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- W2028651663 date "2009-04-05" @default.
- W2028651663 modified "2023-09-27" @default.
- W2028651663 title "Effect of Methylation at the C2 Position of Imidazolium on the Structure of Ionic Liquids Revealed by Large Angle X-ray Scattering Experiments and MD Simulations" @default.
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- W2028651663 doi "https://doi.org/10.1246/cl.2009.340" @default.
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