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- W2028671194 abstract "Abstract New organoaluminium compounds containing P v NMeAl bonds, diethylaluminium dialkyl N -methylphosphoramidate, (RO) 2 P(O)NMeAlEt 2 , and tetraalkylphosphorodiamidic N -methylamide, (R 2 N) 2 P(O)NMeAlEt 2 , were prepared. Cryoscopic measurements showed these compounds to be dimeric by intermolecular coordination. The introduction of bulky substituents on the phosphorus atom decreased the degree of association. The coordination of oxygen atom of PO bonds to organoaluminium moiety was indicated by spectroscopic evidence. In the reactions of (RO) 2 P(O)NMeAlEt 2 with aromatic aldehydes or phenyl isocyanate, the corresponding imino compounds were obtained by an addition—elimination process." @default.
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- W2028671194 date "1974-08-01" @default.
- W2028671194 modified "2023-09-24" @default.
- W2028671194 title "Preparation and iminocarbonylation reactions of organoaluminium chelate compounds containing PvNMeAl bonds" @default.
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- W2028671194 doi "https://doi.org/10.1016/s0022-328x(00)84631-8" @default.
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