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• W2028671502 abstract "The retention selectivity of graphitic carbon packing materials was compared with those of octadecylsilyl- and pyrenylethylsilylsilica packing materials in reversed-phase liquid chromatography. A carbon stationary phase showed the highest hydropobicity and selective retention of planar, unsaturated compounds. The presence of hydrophilic groups did not cause as great a retention decrease on carbon as on silica-based materials. A much greater influence of structural planarity of solutes was observed with carbon than with silica-based phases, presumably because the solute planarity emphasizes the interaction with the graphite surface based on charge transfer and dispersion forces. Pyrenylethyl-bonded silica gel was found to be intermediate between alkylsilica and graphitized carbon packing materials with respect to the selectivity based on the electronic steric interaction with the fused-ring aromatic systems on the stationary phase." @default.
• W2028671502 created "2016-06-24" @default.
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• W2028671502 date "1991-01-01" @default.
• W2028671502 modified "2023-10-17" @default.
• W2028671502 title "Selectivity of carbon packing materials in comparison with octadecylsilyl- and pyrenylethylsilylsilica gels in reversed- phase liquid chromatography" @default.
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• W2028671502 doi "https://doi.org/10.1016/s0021-9673(00)91416-x" @default.
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