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- W2028674717 endingPage "8343" @default.
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- W2028674717 abstract "The experimental and theoretical bases for a synchronous or concerted double-proton transfer in centro-symmetric H-bonded electronically excited molecular dimers are presented. The prototype model is the 7-azaindole dimer. New research offers confirmation of a concerted mechanism for excited-state biprotonic transfer. Recent femtosecond photoionization and coulombic explosion techniques have given rise to time-of-flight MS observations suggesting sequential two-step biprotonic transfer for the same dimer. We interpret the overall species observed in the time-of-flight experiments as explicable without conflict with the concerted mechanism of proton transfer." @default.
- W2028674717 created "2016-06-24" @default.
- W2028674717 creator A5027047181 @default.
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- W2028674717 date "1999-07-20" @default.
- W2028674717 modified "2023-10-16" @default.
- W2028674717 title "Resolution of concerted versus sequential mechanisms in photo-induced double-proton transfer reaction in 7-azaindole H-bonded dimer" @default.
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- W2028674717 doi "https://doi.org/10.1073/pnas.96.15.8338" @default.
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