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- W2028675144 abstract "The first examples of fluoro, pseudobalogeno, and carboxylatopalladium(IV) complexes have been obtained by the exchange of the bromo ligand in PdBrMe2(CH2Ph)bpy) (bpy = 2,2′-bipyridyl) on addition of a silver salt, or silver nitrate and the appropriate anion, in acetonitrile. The syntheses have permitted a study of the effect of groups X on the selectivity in reductive elimination of ethane and ethylbenzene from PdXMe2(CH2Ph)bpy). For X Br, N3, SCN, or O2CPh, reductive elimination from the unstable palladium(IV) complexes in acetone gives ethane and PdX(CH2Ph)(bpy) only, but these products together with ca. 10% of ethylbenzene and PdXMe(bpy) are formed from the complexes PdXMe2(CH2Ph) (bpy) (X F, Cl, I, OCN, SeCN, O2CCF3). The binding mode of the ambidentate pseudohalides OCN−, SCN− and SeCN− has not been determined." @default.
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- W2028675144 date "1992-07-01" @default.
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- W2028675144 title "Synthesis of halogeno, pseudohalogeno, and carboxylatopalladium(IV) complexes by halogen exchange. Crystal structure of azido(2,2′-bipyridyl)- benzylpalladium(II), formed on reductive elimination of ethane from Pd(N3)Me2(CH2Ph)(bpy)" @default.
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- W2028675144 doi "https://doi.org/10.1016/0022-328x(92)80143-l" @default.
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