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- W2028690634 endingPage "7816" @default.
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- W2028690634 abstract "We have found that a positive muon (${ensuremath{mu}}^{+}$) implanted into LiF, NaF, Ca${mathrm{F}}_{2}$, or Ba${mathrm{F}}_{2}$ pulls two ${mathrm{F}}^{ensuremath{-}}$ ions together in a strong hydrogen bond until the $^{19}mathrm{F}$ nuclei are separated by roughly twice the nominal ${mathrm{F}}^{ensuremath{-}}$ ionic radius, with the ${ensuremath{mu}}^{+}$ midway between. The resultant $mathrm{F}ensuremath{mu}mathrm{F}$ center is easily observed via the distinctive behavior of the collinear $^{19}mathrm{F}:{ensuremath{mu}}^{+}:^{19}mathrm{F}$ spin system (coupled by dipole-dipole interactions between the muon and the fluorine nuclei) in both transverse-field muon-spin rotation and zero-field muon-spin relaxation experiments. We speculate that implanted ${mathrm{H}}^{+}$ ions may initially form similar hydrogen bonds between adjacent ${mathrm{F}}^{ensuremath{-}}$ ions in many metal fluoride crystals." @default.
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- W2028690634 date "1986-06-01" @default.
- W2028690634 modified "2023-09-26" @default.
- W2028690634 title "Observation of muon-fluorine hydrogen bonding in ionic crystals" @default.
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- W2028690634 doi "https://doi.org/10.1103/physrevb.33.7813" @default.
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