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- W2028736075 abstract "The authors report the intrinsic problem of bifunctional organocatalysts containing acid-base functionalities in one molecule. The enantioselectivity of catalyst 3 for the desymmetrization of anhydride 1 could be increased from 55.5:45.5 er to 97.5:2.5 er by optimizing the reaction conditions. Self-association phenomenon of catalysts 3 and 7 can be prevented by installing a bulky substituent with squaramide catalyst 10. Also, the authors attempted to quantify the degree of self-association by DOSY NMR." @default.
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- W2028736075 date "2010-08-23" @default.
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- W2028736075 title "Higher Enantioselectivity with Less Catalyst Loading" @default.
- W2028736075 doi "https://doi.org/10.1055/s-0030-1257972" @default.
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