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- W2028743084 abstract "We measured the density and liquid-phase CO2 mole fraction of CO2-expanded ketones (acetone, methyl ethyl ketone, methyl propyl ketone, methyl butyl ketone, methyl i-propyl ketone, and t-methyl butyl ketone) at 40 °C and evaluated the expansion coefficient on the basis of the experimental results. Volume expansion was slow in the region of a low carbon dioxide mole fraction (<0.7) but rapid in the region of a high carbon dioxide mole fraction (>0.7). The dependence of the expansion coefficient on the carbon dioxide mole fraction could be attributed to the number of molecules in a certain volume. These phenomena were inferred from the partial molar volume estimated using the Peng–Robinson equation of state (PR-EOS)." @default.
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- W2028743084 date "2010-11-01" @default.
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- W2028743084 title "Dependence of volume expansion on alkyl chain length and the existence of branched methyl group of CO2-expanded ketone systems at 40°C" @default.
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- W2028743084 doi "https://doi.org/10.1016/j.supflu.2010.05.025" @default.
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