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- W2028766243 abstract "Synthesis of cellulose graft copolymers with mixtures of N-vinyllactams (VL) and vinyl monomers (VM), the definition of the copolymer composition of the grafted chain, coefficients of relative monomers reactiveness, solubility, characteristic viscosity, and the effect of the initial monomer ratio on the obtained products properties are reported.N-vinylpirrolidone, N-vinylcaprolactam, and methylmethacrylate butylmethacrylate, acrylonitrile, and β-hydroxyacrylate glycidic ether were used in the investigations as well as preparations of cotton fibers, fibers of diacetylcellulose, and fibers of viscose staple rayon.VL and VM were grafted onto cellulose in the oxidative-reductive systems of bivalent ferrous and hydrogen peroxide at various molar ratio (0.1:0.9; 0.25:0.75; 0.5:0.5; 0.75:0.25; 0.9:0.1). The VL-VM copolymer side chains were hydrolytically isolated from the grafted part of cellulose. The values of rVL and rVM were plotted as those of rVL and rVM for the static polymerization. It is found that the composition of the grafted cellulose side chains was identical with that of the copolymers, which have been obtained by the bulk method. The copolymers solubility remained the same after the grafted cellulose chain was isolated by the classic method of copolymerization in the absence of cellulose.The graft copolymers were identified by IR spectra. The mechanism of the graft copolymerization is given for all the abovementioned monomers and cellulose." @default.
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- W2028766243 date "2007-03-07" @default.
- W2028766243 modified "2023-09-25" @default.
- W2028766243 title "Synthesis of cellulose graft copolymers with mixtures of N-vinyllactams and vinyl monomers" @default.
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- W2028766243 doi "https://doi.org/10.1002/polc.5070370114" @default.
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