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- W2028807004 abstract "A set of valence force constants is calculated for the P2O74− ion in β-Mg2P2O7 and a group of MIVP2O7 compounds typified by ZrP2O7. The results agree generally with the relationships between bond orders and stretching force constants suggested by Cruickshank and Robinson. Bond distances calculated from the stretching force constants are in excellent agreement with observed PO bond distances in the MIVP2O7 compounds, but not in β-Mg2P2O7. The values of the bending force constants support Lazerev's contention that the bridging oxygen is not firmly fixed in a linear POP configuration." @default.
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- W2028807004 date "1969-04-01" @default.
- W2028807004 modified "2023-10-14" @default.
- W2028807004 title "Valence force constants for the P2O74− ion in MIVP2O7 and M2IIP2O7 solids" @default.
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- W2028807004 doi "https://doi.org/10.1016/0022-1902(69)80140-5" @default.
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