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- W2028824613 abstract "Aryl or allyl ethers of some heterocyclic systems can be readilyhydrogenolysed or cross-coupled catalytically with transition metals togive arenes, alkenes or alkanes. Unexpectedly for transition metals, thecorresponding alkyl and, particularly, benzyl ethers are totally inert.An X-ray structure determination on 3-benzyloxy-1,2-benzisothiazole1,1-dioxide 1 has shown that there is no inherent structural reason forthis major difference, apart from the absence of a suitable p-orbital inthe benzyl ethers." @default.
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- W2028824613 date "1997-01-01" @default.
- W2028824613 modified "2023-09-25" @default.
- W2028824613 title "Metal-assisted reactions. Part 27.1 3-Benzyloxy-1,2-benzisothiazole 1,1-dioxide: an unusual ether linkage that does not permit heterogeneous catalytic hydrogenolysis" @default.
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- W2028824613 doi "https://doi.org/10.1039/a701672g" @default.
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