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• W2028843487 abstract "The chemistry of nitro- and amine-substituted aromatic molecules on a Cu(110) surface has been studied using Fourier transform infrared spectroscopy, by comparison of the adsorption of nitrobenzene (NB), p-dinitrobenzene (pDNB) and p-nitroaniline (pNA). When nitrobenzene was adsorbed on a clean Cu(110) surface at room temperature, it decomposed to form a phenyl species with the C2 axis nearer the surface normal than parallel. At 83 K, multilayer nitrobenzene formed with a vibrational spectrum, in good agreement with gas-phase data; upon warming, a phenyl species remained, which was stable to about 350 K. AES of the species present following dosing at 300 K showed carbon and oxygen but no nitrogen. When p-dinitrobenzene was adsorbed it decomposed, losing one NO2, to form a stable nitrophenyl species on Cu(110) orientated with the C2 axis closer to the surface normal than the phenyl species derived from nitrobenzene. In contrast, p-nitroaniline does not decompose on the Cu(110) surface at room temperature. Multilayer and monolayer p-nitroaniline are distinguished by frequency shifts of NO2 and NH2 modes, attributed to intermolecular hydrogen bonding. In the monolayer, the amine group appears to stabilise the ring-nitro group bond, allowing bonding to the surface via the NO2 group in an orientation perpendicular to the surface." @default.
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• W2028843487 date "1996-12-01" @default.
• W2028843487 modified "2023-10-01" @default.
• W2028843487 title "Adsorption of nitrobenzene and some simple derivatives on the Cu(110) surface" @default.
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• W2028843487 doi "https://doi.org/10.1016/s0039-6028(96)01068-0" @default.
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