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• W2028843598 abstract "Abstract Reactions of the zinc(I) complex [Zn 2 (Mesnacnac) 2 ] (Mesnacnac=[(2,4,6‐Me 3 C 6 H 2 )NC(Me)] 2 CH) with solid K 3 Bi 2 dissolved in liquid ammonia yield crystals of the compound K 4 [ZnBi 2 ]⋅(NH 3 ) 12 ( 1 ), which contains the molecular, linear heteroatomic [BiZnBi] 4− polyanion ( 1 a ). This anion represents the first example of a three‐atomic molecular ion of metal atoms being iso(valence)‐electronic to CO 2 and being synthesized in solution. The analogy of the discrete [BiZnBi] 4− anion and the polymeric ${{{hfill 1atop hfill infty }}}$ [(ZnBi 4/2 ) 4− ] unit to monomeric CO 2 and polymeric SiS 2 is rationalized." @default.
• W2028843598 created "2016-06-24" @default.
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• W2028843598 date "2014-07-02" @default.
• W2028843598 modified "2023-10-18" @default.
• W2028843598 title "BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)-electronic to CO₂" @default.
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• W2028843598 doi "https://doi.org/10.1002/anie.201404343" @default.
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