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- W2028856630 abstract "Abstract Toll-like receptors (TLRs) play important roles in host immune defense, and synthetic TLR ligands are useful therapeutic agents for a variety of diseases including infection, inflammation, and cancers. Alginates are strong immune stimulants mediated by TLR2/4. Reported here are the design and chemical synthesis of two glycosides (1 and 2) containing β-1,4-di- d -mannuronic acid moiety derived from alginate. The synthesis features the preparation of β-1,4- d -mannobiose derivatives through diastereoselective β-glycosylation of 4,6-di-O-benzylidene protected thiomannoside donor 7, followed by an oxidation step using TEMPO/BAIB to provide the β-1,4-di- d -mannuronic acid moiety." @default.
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- W2028856630 date "2007-04-01" @default.
- W2028856630 modified "2023-09-27" @default.
- W2028856630 title "Synthesis of β-1,4-di-d-mannuronic acid glycosides as potential ligands for toll-like receptors" @default.
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- W2028856630 doi "https://doi.org/10.1016/j.tetlet.2007.02.086" @default.
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