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• W2028876885 startingPage "10532" @default.
• W2028876885 abstract "[structure: see text] Attractive interactions between substituted arenes in the parallel displaced configuration have been quantitatively studied using triptycene-derived molecular conformational reporters. Charge-transfer bands are observed for models where the interactions are between strong donor and acceptors. Substituent effects on the strength of the aromatic interaction follow opposite trends for strongly electron-deficient arenes and mildly perturbed arenes. The free energy of interactions for models with strong electron donors and acceptors does not follow a linear correlation in the Hammett plot. Electrostatic models alone do not account for the nonlinearity of the free energy-substituents plot." @default.
• W2028876885 created "2016-06-24" @default.
• W2028876885 creator A5033025385 @default.
• W2028876885 creator A5067333998 @default.
• W2028876885 creator A5080850535 @default.
• W2028876885 date "2005-11-09" @default.
• W2028876885 modified "2023-09-27" @default.
• W2028876885 title "A Threshold for Charge Transfer in Aromatic Interactions? A Quantitative Study of π-Stacking Interactions" @default.
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• W2028876885 doi "https://doi.org/10.1021/jo051808a" @default.
• W2028876885 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16323868" @default.
• W2028876885 hasPublicationYear "2005" @default.
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