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- W2028896739 abstract "Abstract In this work, the Dehghani–Modarress mean spherical approximation model has been modified and extended for prediction of the mean ionic activity coefficient in mixed aqueous electrolyte solutions at different temperatures. In the DM-MSA model the cationic diameter as well as the dielectric constant of water are considered to be concentration dependent. In order to make the DM-MSA model applicable in engineering applications, a binary interaction parameter has been introduced. Using these parameters, the mean ionic activity coefficient of electrolytes can be predicted applying a linear mixing rule. To calculate the activity coefficient of single electrolytes at different temperatures, a temperature dependency has been considered for cationic size as well as dielectric constant. Utilizing the obtained parameters for single electrolytes at different temperatures, the mean ionic activity coefficients of mixed electrolytes have been predicted. The accuracy of the model is also compared with those results produced by extended UNIQUAC model. In order to have a fair judgment, the same experimental data and minimization algorithm have been used for comparison." @default.
- W2028896739 created "2016-06-24" @default.
- W2028896739 creator A5022438008 @default.
- W2028896739 creator A5075895389 @default.
- W2028896739 date "2012-05-01" @default.
- W2028896739 modified "2023-09-27" @default.
- W2028896739 title "A modified mean spherical approximation model for prediction of mean ionic activity coefficient in mixed electrolyte solution at different temperatures" @default.
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- W2028896739 doi "https://doi.org/10.1016/j.fluid.2012.02.021" @default.
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