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- W2028901409 abstract "A detailed study has been carried out of pure films of cholesterol, 3-doxyl cholestane (3-DC), 3-doxyl 17-hydroxyl androstane (3-DA), tetradecanoic acid and dipalmitoylphosphatidylcholine (DPPC), in the 20–45°C temperature range. The resemblence between pure films of cholesterol and the β-epimer of 3-DC is quite striking. Where molecular packing and hydrophobic interactions are concerned, the two molecules behave in a similar way. Where surface potentials or dipole moments are concerned the differences are consistent with the differing polar groups. In contrast, 3-DA differs substantially in its film behavior from that of either cholesterol or 3-DC. The differences can be ascribed both to the bipolar nature of 3-DA and its lack of an alkane chain at the C17 steroid position. Based on these differences we ascribe the bulk of cholesterol's small coefficient of thermal expansion to its possessing an alkane chain." @default.
- W2028901409 created "2016-06-24" @default.
- W2028901409 creator A5033411183 @default.
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- W2028901409 date "1979-11-01" @default.
- W2028901409 modified "2023-10-16" @default.
- W2028901409 title "Molecular packing in steroid-lecithin monolayers, part I: Pure films of cholesterol, 3-doxyl-cholestane, 3-doxyl-17-hydroxyl-androstane, tetradecanoic acid and dipalmitoyl-phosphatidylcholine" @default.
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- W2028901409 doi "https://doi.org/10.1016/0009-3084(79)90113-0" @default.
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