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• W2028902966 abstract "Abstract A new, catalytic methodology for the synthesis of heterobiaryls by the ruthenium‐catalyzed CH activation/cross‐coupling of heterocyclic amides with aryl boroneopentylates is surveyed. From this survey, the highly regioselective reaction of furan‐3‐carboxamide to give 2‐aryl‐3‐furanamides is optimized and generalized in scope with respect to the aryl boroneopentylate coupling partners. Established thereby is a one‐step synthetic method which may supercede the broadly applied two‐step directed ortho metalation (DoM)–cross coupling reaction involving cryogenic and strong base conditions and which has potential for further ortho and remote metalation chemistry. magnified image" @default.
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• W2028902966 date "2014-04-30" @default.
• W2028902966 modified "2023-10-15" @default.
• W2028902966 title "CH Activation by Amide Chelation Control: Ruthenium‐ Catalyzed Direct Synthesis of 2‐Aryl‐3‐furanamides" @default.
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• W2028902966 doi "https://doi.org/10.1002/adsc.201400147" @default.
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