FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2028921405> ?p ?o ?g. }

• W2028921405 endingPage "2211" @default.
• W2028921405 startingPage "2198" @default.
• W2028921405 abstract "We study monolayers formed at an air−water interface on a Langmuir trough by telechelic poly(ethylene oxide) polymers end capped with hydrophobic alkane groups (C12 and C16). The pressure−area isotherms show two plateaus: the first plateau at low coverage already exists for nontelechelic PEO and is attributed to the formation of loops in the solution; after this plateau, the pressure rises stongly as the hydrophobic groups anchor the polymers on the surface, which leads to the formation of a grafted polymer layer; the second plateau at high density is due to a dissolution of the polymer chains in the bulk water. Starting from a monolayer at high density, we also study experimentally the relaxation of the surface pressure with time due to the dissolution of the polymer. A theoretical approach of this problem based on polymer brush theory is proposed. Both the static properties of the layer and the desorption kinetics are calculated. The model accounts well for the shape of the isotherms and for the relaxation kinetics. It gives a good interpretation of the role of various parameters such as the compression velocity, the molecular weight, and the hydrophobicity of the chain ends. The anchoring energy of the hydrophobic groups is determined by comparison with experiments." @default.
• W2028921405 created "2016-06-24" @default.
• W2028921405 creator A5012305263 @default.
• W2028921405 creator A5046357655 @default.
• W2028921405 creator A5075663646 @default.
• W2028921405 date "1998-03-20" @default.
• W2028921405 modified "2023-10-14" @default.
• W2028921405 title "Polymer Brushes Formed by End-Capped Poly(ethylene oxide) (PEO) at the Air−Water Interface" @default.
• W2028921405 cites W1978578508 @default.
• W2028921405 cites W1985417358 @default.
• W2028921405 cites W1994678315 @default.
• W2028921405 cites W2006102261 @default.
• W2028921405 cites W2018496095 @default.
• W2028921405 cites W2021087272 @default.
• W2028921405 cites W2027781769 @default.
• W2028921405 cites W2028213113 @default.
• W2028921405 cites W2040904943 @default.
• W2028921405 cites W2044414287 @default.
• W2028921405 cites W2046171220 @default.
• W2028921405 cites W2048829852 @default.
• W2028921405 cites W2054087287 @default.
• W2028921405 cites W2069960852 @default.
• W2028921405 cites W2072062732 @default.
• W2028921405 cites W2079826474 @default.
• W2028921405 cites W2094102762 @default.
• W2028921405 cites W2138674543 @default.
• W2028921405 cites W2147027871 @default.
• W2028921405 doi "https://doi.org/10.1021/ma971665x" @default.
• W2028921405 hasPublicationYear "1998" @default.
• W2028921405 type Work @default.
• W2028921405 sameAs 2028921405 @default.
• W2028921405 citedByCount "77" @default.
• W2028921405 countsByYear W20289214052012 @default.
• W2028921405 countsByYear W20289214052013 @default.
• W2028921405 countsByYear W20289214052014 @default.
• W2028921405 countsByYear W20289214052015 @default.
• W2028921405 countsByYear W20289214052016 @default.
• W2028921405 countsByYear W20289214052017 @default.
• W2028921405 countsByYear W20289214052018 @default.
• W2028921405 countsByYear W20289214052019 @default.
• W2028921405 countsByYear W20289214052020 @default.
• W2028921405 countsByYear W20289214052021 @default.
• W2028921405 crossrefType "journal-article" @default.
• W2028921405 hasAuthorship W2028921405A5012305263 @default.
• W2028921405 hasAuthorship W2028921405A5046357655 @default.
• W2028921405 hasAuthorship W2028921405A5075663646 @default.
• W2028921405 hasConcept C127413603 @default.
• W2028921405 hasConcept C147789679 @default.
• W2028921405 hasConcept C150394285 @default.
• W2028921405 hasConcept C15744967 @default.
• W2028921405 hasConcept C15920480 @default.
• W2028921405 hasConcept C159985019 @default.
• W2028921405 hasConcept C162711632 @default.
• W2028921405 hasConcept C166940927 @default.
• W2028921405 hasConcept C171250308 @default.
• W2028921405 hasConcept C178790620 @default.
• W2028921405 hasConcept C185592680 @default.
• W2028921405 hasConcept C188027245 @default.
• W2028921405 hasConcept C192562407 @default.
• W2028921405 hasConcept C2776029896 @default.
• W2028921405 hasConcept C2777801237 @default.
• W2028921405 hasConcept C2779851234 @default.
• W2028921405 hasConcept C2781018886 @default.
• W2028921405 hasConcept C42360764 @default.
• W2028921405 hasConcept C44228677 @default.
• W2028921405 hasConcept C521977710 @default.
• W2028921405 hasConcept C7070889 @default.
• W2028921405 hasConcept C77805123 @default.
• W2028921405 hasConcept C88380143 @default.
• W2028921405 hasConceptScore W2028921405C127413603 @default.
• W2028921405 hasConceptScore W2028921405C147789679 @default.
• W2028921405 hasConceptScore W2028921405C150394285 @default.
• W2028921405 hasConceptScore W2028921405C15744967 @default.
• W2028921405 hasConceptScore W2028921405C15920480 @default.
• W2028921405 hasConceptScore W2028921405C159985019 @default.
• W2028921405 hasConceptScore W2028921405C162711632 @default.
• W2028921405 hasConceptScore W2028921405C166940927 @default.
• W2028921405 hasConceptScore W2028921405C171250308 @default.
• W2028921405 hasConceptScore W2028921405C178790620 @default.
• W2028921405 hasConceptScore W2028921405C185592680 @default.
• W2028921405 hasConceptScore W2028921405C188027245 @default.
• W2028921405 hasConceptScore W2028921405C192562407 @default.
• W2028921405 hasConceptScore W2028921405C2776029896 @default.
• W2028921405 hasConceptScore W2028921405C2777801237 @default.
• W2028921405 hasConceptScore W2028921405C2779851234 @default.
• W2028921405 hasConceptScore W2028921405C2781018886 @default.
• W2028921405 hasConceptScore W2028921405C42360764 @default.
• W2028921405 hasConceptScore W2028921405C44228677 @default.
• W2028921405 hasConceptScore W2028921405C521977710 @default.
• W2028921405 hasConceptScore W2028921405C7070889 @default.
• W2028921405 hasConceptScore W2028921405C77805123 @default.
• W2028921405 hasConceptScore W2028921405C88380143 @default.
• W2028921405 hasIssue "7" @default.
• W2028921405 hasLocation W20289214051 @default.
• W2028921405 hasLocation W20289214052 @default.
• W2028921405 hasLocation W20289214053 @default.
• W2028921405 hasOpenAccess W2028921405 @default.
• W2028921405 hasPrimaryLocation W20289214051 @default.

• next