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- W2028933927 abstract "Silica-bound cis-dicarbonyl-μ-chloro [μ-[2-(trioxysilyl)ethanethiolato-S:S]bis[tris(1,1-dimethylethyl)phosphine]dirhodium (1) was shown to catalyze the disproportionation of 1,3-cyclohexadiene and of 1,2-dihydro-naphthalenes, accompanied by ⩽10% dehydrogenation. The formation of tetralins and naphthalenes was found to be strongly affected by the electronic nature of the starting 1,2-dihydronaphthalene derivatives. The effect of hydroxylic solvents on the disproportionation reaction was demonstrated by application of CD3OD. A mechanism which involves both metallic centers of the dinuclear complex is proposed." @default.
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- W2028933927 date "1990-07-01" @default.
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- W2028933927 title "Disproportionation of 1,3-cyclohexadiene and 1,2-dihydronaphthalene derivatives by a silica-bound dirhodium catalyst" @default.
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- W2028933927 doi "https://doi.org/10.1016/0304-5102(90)85189-o" @default.
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