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- W2028982561 abstract "This article reports the cointercalation of acrylic acid (AA) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) in the interlayer region of Mg2Al layered double hydroxide (LDH) and the application of this inorganic–organic composite material in the field of water superabsorbent. The monomers of AA and AMPS were cointercalated into galleries of Mg2Al−LDH (denoted as AA−AMPS/LDH) with various molar ratios by ion-exchange method, which was confirmed by powder X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), and elemental analysis. The polymer-based superabsorbent was prepared through in situ free-radical aqueous copolymerization of AA and AMPS, with AA−AMPS/LDH as additive, N,N′-methylenebisacrylamide (NMBA) as crosslinker and potassium persulfate (KPS) as initiator. The composition of this poly(AA-co-AMPS)/LDH was demonstrated as a good water superabsorbent. The LDH content, water absorbency, thermal stability, and swelling rate of this superabsorbent were also investigated in detail. Results showed that the incorporation of a 5 wt % AA−AMPS/LDH into polymer matrix increased its water absorbency significantly by 27.7% (in water) and by 51.5% (in 0.9 wt % NaCl solution). © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011" @default.
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- W2028982561 date "2011-03-04" @default.
- W2028982561 modified "2023-10-14" @default.
- W2028982561 title "Preparation of acrylic acid and AMPS cointercalated layered double hydroxide and its application for superabsorbent" @default.
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- W2028982561 doi "https://doi.org/10.1002/app.33739" @default.
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