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- W2028984960 abstract "Carbonate-assisted hydrolysis of Y or Yb(III) ions in the presence of the trivacant Wells-Dawson polyoxoanion, alpha-[P(2)W(15)O(56)](12-), produced two polyoxometalate-supported Y- or Yb(III)-hydroxo/oxo clusters, which have been characterized by single-crystal X-ray structure determination. The structure of the Y complex consists of a distorted Y(4)(OH)(4) cubane cluster encapsulated by two lacunary alpha-[P(2)W(15)O(56)](12-) units, while the Yb cluster features a hexametallic core centered around a mu(6)-oxo atom with each Yb(3)(III) triangular face capped by an oxo or a hydroxo group. Magnetization measurements of the ytterbium(III) derivative suggested that intermolecular dipolar exchange is present at low temperatures (below 15 K). Despite its absence in the structures themselves, control experiments show that carbonate not only functions in the hydrolysis, it also influences the structure of the complexes by complexation to yttrium and the f-block elements." @default.
- W2028984960 created "2016-06-24" @default.
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- W2028984960 date "2005-01-07" @default.
- W2028984960 modified "2023-10-14" @default.
- W2028984960 title "Polyoxometalate-Supported Y- and YbIII-Hydroxo/Oxo Clusters from Carbonate-Assisted Hydrolysis" @default.
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- W2028984960 doi "https://doi.org/10.1002/chem.200400774" @default.
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