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- W2028989830 endingPage "8497" @default.
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- W2028989830 abstract "Ruthenium-catalyzed allylic alkylations are an interesting alternative to palladium-catalyzed processes, since they can provide products which are not accessible under Pd-catalysis. Chiral terminal allylic substrates can be reacted with perfect stereo- and regioretention, and also (Z)-configured allylic substrates can be converted isomerization-free. This allows highly stereoselective modifications of peptides at glycine subunits. The configuration at the α-position of the new generated α-amino acid can be controlled by the chiral peptide chain, and at the β-position by using chiral allylic substrates." @default.
- W2028989830 created "2016-06-24" @default.
- W2028989830 creator A5004714618 @default.
- W2028989830 creator A5088253534 @default.
- W2028989830 date "2014-08-21" @default.
- W2028989830 modified "2023-10-17" @default.
- W2028989830 title "Selective Peptide Modifications via Ruthenium-Catalyzed Allylic Alkylations" @default.
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- W2028989830 doi "https://doi.org/10.1021/jo501731y" @default.
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