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- W2028992094 abstract "Catalytic combustion of methane has been studied over a library of Pd, Pt, and La in mono-, bi-, and tri-element system supported on γ-Al2O3 washcoated ceramic monolith using an eight-tubular flow reactor. Simulated operating conditions of a small-size gas turbine were employed to investigate the combustion activity. Lead formulations from an initial high throughput screening were classified into two categories: Pd-Pt bi-element catalysts, and Pd-Pt-La tri-element catalysts with relatively constant 20% Pd (equivalent to 1% Pd of 5% total elemental loading). The substitution of Pd by Pt, while maintaining 5% total loading, was observed to improve the combustion activity as expected due to the co-existence of PdO and Pd–Pt alloy on the catalytic surface. However, its combustion activity was only slightly decreased when Pt was further substituted by La with relatively fixed 20% Pd loading due to the metal dilution by La. Nevertheless, the catalyst with Pd and Pt in equivalent amount with three times of La dilution (Pd:Pt:La = 1:1:3) was suggested to be the best formula not only due to its high combustion activity at even low temperatures, but also the reduction of noble metal usage." @default.
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- W2028992094 date "2005-06-01" @default.
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- W2028992094 title "Catalytic methane combustion on Pd-Pt-La catalysts and their surface models" @default.
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- W2028992094 doi "https://doi.org/10.1016/j.apcatb.2004.12.004" @default.
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