Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029003947> ?p ?o ?g. }
- W2029003947 endingPage "5981" @default.
- W2029003947 startingPage "5968" @default.
- W2029003947 abstract "Carbon−halogen (C−X) bonds (X = Cl, Br) can be easily functionalized with ethyl diazoacetate (N2CHCO2Et) in the presence of silver-based catalysts containing the TpxAg core (Tpx = hydrotrispyrazolylborate ligand). Polyhalomethanes are converted into products derived from the formal insertion of the carbene CHCO2Et units into the C−X bond. In the case of monohaloalkanes (C4−C6), cleavage of the C−X bond is observed, with formation of XCH2CO2Et and the corresponding olefin. Experimental evidence and theoretical calculations have led to the proposal of a novel mechanism to account for these transformations, in which the metal participates along the pathway in all the reaction steps. Among the experimental data, the first example of a metal-induced, asymmetric functionalization of a C−Cl bond by carbene insertion is included (ee = 14 ± 2%)." @default.
- W2029003947 created "2016-06-24" @default.
- W2029003947 creator A5007303026 @default.
- W2029003947 creator A5019047795 @default.
- W2029003947 creator A5028002953 @default.
- W2029003947 creator A5044285914 @default.
- W2029003947 creator A5045676433 @default.
- W2029003947 creator A5078170195 @default.
- W2029003947 date "2009-09-11" @default.
- W2029003947 modified "2023-10-17" @default.
- W2029003947 title "The Mechanism of the Catalytic Functionalization of Haloalkanes by Carbene Insertion: An Experimental and Theoretical Study" @default.
- W2029003947 cites W1964186892 @default.
- W2029003947 cites W1964837435 @default.
- W2029003947 cites W1964956355 @default.
- W2029003947 cites W1969506953 @default.
- W2029003947 cites W1973758215 @default.
- W2029003947 cites W1973981367 @default.
- W2029003947 cites W1981263626 @default.
- W2029003947 cites W1988332834 @default.
- W2029003947 cites W1995510822 @default.
- W2029003947 cites W1995747009 @default.
- W2029003947 cites W2004884592 @default.
- W2029003947 cites W2006259165 @default.
- W2029003947 cites W2014794308 @default.
- W2029003947 cites W2019111008 @default.
- W2029003947 cites W2020226465 @default.
- W2029003947 cites W2023271753 @default.
- W2029003947 cites W2025914756 @default.
- W2029003947 cites W2028722175 @default.
- W2029003947 cites W2032244659 @default.
- W2029003947 cites W2032900743 @default.
- W2029003947 cites W2033990154 @default.
- W2029003947 cites W2034876331 @default.
- W2029003947 cites W2035797527 @default.
- W2029003947 cites W2043653704 @default.
- W2029003947 cites W2044490585 @default.
- W2029003947 cites W2046963202 @default.
- W2029003947 cites W2050511290 @default.
- W2029003947 cites W2058680650 @default.
- W2029003947 cites W2059557165 @default.
- W2029003947 cites W2059819176 @default.
- W2029003947 cites W2068813542 @default.
- W2029003947 cites W2071875569 @default.
- W2029003947 cites W2075768816 @default.
- W2029003947 cites W2082712943 @default.
- W2029003947 cites W2088309473 @default.
- W2029003947 cites W2095828279 @default.
- W2029003947 cites W2097650793 @default.
- W2029003947 cites W2116350131 @default.
- W2029003947 cites W2122158601 @default.
- W2029003947 cites W2124713517 @default.
- W2029003947 cites W2143981217 @default.
- W2029003947 cites W2147757993 @default.
- W2029003947 cites W2148273332 @default.
- W2029003947 cites W2148284063 @default.
- W2029003947 cites W2148670197 @default.
- W2029003947 cites W2148924072 @default.
- W2029003947 cites W2168439556 @default.
- W2029003947 cites W2322145898 @default.
- W2029003947 cites W2329022429 @default.
- W2029003947 cites W2329309665 @default.
- W2029003947 cites W2335548883 @default.
- W2029003947 cites W2593005722 @default.
- W2029003947 cites W2748402918 @default.
- W2029003947 cites W2949263493 @default.
- W2029003947 cites W2951026489 @default.
- W2029003947 cites W2951422857 @default.
- W2029003947 cites W2951899654 @default.
- W2029003947 cites W2953380043 @default.
- W2029003947 cites W3004938745 @default.
- W2029003947 cites W4233418988 @default.
- W2029003947 cites W4251038450 @default.
- W2029003947 doi "https://doi.org/10.1021/om9006888" @default.
- W2029003947 hasPublicationYear "2009" @default.
- W2029003947 type Work @default.
- W2029003947 sameAs 2029003947 @default.
- W2029003947 citedByCount "47" @default.
- W2029003947 countsByYear W20290039472012 @default.
- W2029003947 countsByYear W20290039472013 @default.
- W2029003947 countsByYear W20290039472014 @default.
- W2029003947 countsByYear W20290039472015 @default.
- W2029003947 countsByYear W20290039472016 @default.
- W2029003947 countsByYear W20290039472017 @default.
- W2029003947 countsByYear W20290039472018 @default.
- W2029003947 countsByYear W20290039472019 @default.
- W2029003947 countsByYear W20290039472020 @default.
- W2029003947 countsByYear W20290039472021 @default.
- W2029003947 countsByYear W20290039472022 @default.
- W2029003947 countsByYear W20290039472023 @default.
- W2029003947 crossrefType "journal-article" @default.
- W2029003947 hasAuthorship W2029003947A5007303026 @default.
- W2029003947 hasAuthorship W2029003947A5019047795 @default.
- W2029003947 hasAuthorship W2029003947A5028002953 @default.
- W2029003947 hasAuthorship W2029003947A5044285914 @default.
- W2029003947 hasAuthorship W2029003947A5045676433 @default.
- W2029003947 hasAuthorship W2029003947A5078170195 @default.
- W2029003947 hasConcept C115537861 @default.
- W2029003947 hasConcept C137955730 @default.