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- W2029005166 abstract "Abstract (3-(Alkoxycarbonyl)-2-ethoxy-2-propenylidene)triphenylphosphorane reacted with diacylethylenes to give 2-ethoxycyclopentadienes as a 1:1 mixture of the 1,3- and 1,4-dienes, which were converted upon mild acid treatment into cyclopentenones in a single form. Use of acylmethylenemalonate as an unsymmetrical substrate provides an excellent route to substituted cyclopentenones. An application of the annulation to synthesis of (±)-methyl dehydrojasmonate is also described." @default.
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- W2029005166 date "2010-08-17" @default.
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- W2029005166 title "ChemInform Abstract: Cyclopentenones from 2-Ethoxyallylidene(triphenyl)phosphorane and 1,2- Diacylethylenes: Synthesis of (.+-.)-Methyl Dehydrojasmonate." @default.
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- W2029005166 doi "https://doi.org/10.1002/chin.199539106" @default.
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